D-Camphorsulfonic Acid CAS 3144-16-9

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D-Camphorsulfonic Acid CAS 3144-16-9
Details
MF: C10H16O4S
MW: 232.3
EINECS: 252-817-9
Category
Other Intermediates
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Description

(1R)-(-)-10-Camphorsulfonic acid Basic information

Product Name:

(1R)-(-)-10-Camphorsulfonic acid

Synonyms:

(-)-CAMPHOR-10-SULPHONIC ACID;(-)-CAMPHOR-10-SULFONIC ACID;L-10-(-)-CAMPHOR SULFONIC ACID;L-(-)-CAMPHORSULFONIC ACID;L-(+)-CAMPHOR SULFONIC ACID;L(+)-CAMPHORSULPHONIC ACID;L-CAMPHORSULPHONIC ACID;L-(-)-CAMPHOR-10-SULFONIC ACID

CAS:

35963-20-3

MF:

C10H16O4S

MW:

232.3

EINECS:

252-817-9

 

(1R)-(-)-10-Camphorsulfonic acid Chemical Properties

Melting point 198 °C (dec.)(lit.)
alpha -22 º (c=20,H2O)
Boiling point 344.46°C (rough estimate)
density 1.2981 (rough estimate)
refractive index -21.5 ° (C=5, H2O)
storage temp. Store below +30°C.
solubility DMSO (Slightly), Methanol (Slightly), Water (Sparingly)
pka 1.17±0.50(Predicted)
form Crystalline Powder
color White to slightly beige
PH 1.2-1.4 (20g/l, H2O)
optical activity [α]20/D 21°, c = 2 in H2O
Water Solubility soluble

 

(1R)-(-)-10-Camphorsulfonic acid Usage And Synthesis

Chemical properties

It is a kind of prismatic crystals and its melting point is 193-195 ° C (decompose). It is Insoluble in ether and slightly soluble in glacial acetic acid and ethyl acetate. And it is and moisture in wet air.

Uses

1R)-(-)-10-Camphorsulfonic acid is a chiral derivative of Camphor.It has the following uses:

(1) It is also used for the racemization of optical isomers.
(2) It can be applied to the resolution of intermediate or isomer in medicine.
(3) It also could play a role as organic synthesis intermediates and resolving agent.

 

(1R)-(-)-10-Camphorsulfonic acid Specification

Appearance

White or almost white
crystallir powder

Assay(%)

≥99.0

Melting point(℃)

192-200

Specific Rotation(°)

-21﹣-23

Loss on drying(%)

≤2.0

Iron(mg/kg)

≤20

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